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SOUL/ALLOY Science · Organic Materials

Petrochemical Family Tree

From crude oil through the naphtha cracker, five midstream sisters are born — and the resins and rubbers they raise. One canvas, the whole lineage.

19nodes20links8everyday items

SUPPLY CHAIN · 19 NODES

Petrochemical Family Tree — single-canvas supply chain

From upstream crude oil and naphtha, through the five midstream monomer sisters (ethylene, propylene, butadiene, benzene, p-xylene), to six downstream resins, five synthetic rubbers and one independent natural rubber — 19 nodes connected. Solid lines: single-parent lineages. Dashed lines: convergent lineages with two parents.

Petrochemical Family Tree — single-canvas supply chainFrom upstream crude oil and naphtha, through the five midstream monomer sisters (ethylene, propylene, butadiene, benzene, p-xylene), to six downstream resins, five synthetic rubbers and one independent natural rubber — 19 nodes connected. Solid lines: single-parent lineages. Dashed lines: convergent lineages with two parents.Upstream — crude oil and the naphtha-cracker flameMidstream — five monomer sistersDownstream · ResinsDownstream · RubbersCrude oilCrude OilCrude oilupstreamNaphthaNaphthaNaphthaupstreamEthyleneC₂H₄EthylenePropyleneC₃H₆PropyleneButadieneC₄H₆ButadieneBenzeneC₆H₆Benzenep-Xylenep-C₈H₁₀p-XyleneHDPEHDPEHDPELDPELDPELDPEPVCPVCPVCPSPSPSPETPETPETPPPPPPSBRSBRSBRBRBRBRNBRNBRNBREPDMEPDMEPDMIIRIIRIIRNRNRNR
Solid: single-parent lineageDashed: convergent lineage (two monomers join)

UPSTREAM

Upstream — crude oil and the naphtha-cracker flame

Naphtha (C5–C12) is distilled from crude oil and fed into a steam cracker at 800–870°C. In just 0.2–0.4 seconds of pyrolysis, the matriarchs of the family rise from the flame.

Crude oil and naphtha now have their own personas — meet them via the links below.

MIDSTREAM · 5 MONOMERS

Midstream — five monomer sisters

Five monomers born from the cracker. Each has its own double bond or aromatic ring, and each becomes the mother of countless plastics, rubbers, and fibres.

DOWNSTREAM · 12 MATERIALS

Downstream — the lineage of resins and rubbers

Six commodity resins, five synthetic rubbers, and one independent natural rubber. Almost every material around you is a descendant of one of these branches.

REVERSE LOOKUP

Reverse lookup — your everyday objects

PET bottles, shopping bags, tyres, containers… Pick something near you and walk the tree backwards to its molecular ancestors.

PET bottle

A clear bottle moulded from PET — the signature work of the Ethylene × p-Xylene household.

PET
Ancestors: Ethylene · p-xylene

Shopping bag · cling film

Soft, stretchy LDPE and crisp, tough HDPE — twin children of Ethylene.

HDPELDPE
Ancestors: Ethylene

Car tyre

SBR and BR carry friction and bounce, NR absorbs shocks. A trio collaboration of the rubber siblings.

SBRBRNR
Ancestors: Butadiene · Benzene

Plastic containers and caps

Microwave-safe PP, thin and strong HDPE — your kitchen shelf is a duet of two houses.

PPHDPE
Ancestors: Ethylene · Propylene

Polyester clothing

PET spun into fibre — sportswear to fleece, this is where p-Xylene's family shines.

PET
Ancestors: Ethylene · p-xylene

CD/DVD case · foam

Hard, transparent PS is an artistic crystal of Benzene × Ethylene; foamed, it insulates buildings.

PS
Ancestors: Ethylene · Benzene

PVC pipe · window frame

Ethylene's youngest paired with chlorine — the unsung hero of construction and plumbing.

PVC
Ancestors: Ethylene

Nitrile gloves · oil hose

NBR from butadiene × acrylonitrile — oil-resistant star of medical and industrial fields.

NBR
Ancestors: Butadiene · Benzene

SOURCES · REFERENCES

Sources & references

Data on this page draws on government statistics, industry associations, IEA reports, and scientific databases.